Atomic and Molecular Physics Lecture Note

Atomic physics is the subfield of AMO that studies atoms as an isolated system of electrons and an atomic nucleus, while molecular physics is the study of the physical properties of molecules. The term atomic physics is often associated with nuclear power and nuclear bombs, due to the synonymous use of atomic and nuclear in standard English. However, physicists distinguish between atomic physics — which deals with the atom as a system consisting of a nucleus and electrons — and nuclear physics, which considers atomic nuclei alone. The important experimental techniques are the various types of spectroscopy. Molecular physics, while closely related to atomic physics, also overlaps greatly with theoretical chemistry, physical chemistry and chemical physics.^[4]

Both subfields are primarily concerned with electronic structure and the dynamical processes by which these arrangements change. Generally this work involves using quantum mechanics. For molecular physics, this approach is known as quantum chemistry. One important aspect of molecular physics is that the essential atomic orbital theory in the field of atomic physics expands to the molecular orbital theory. Molecular physics is concerned with atomic processes in molecules, but it is additionally concerned with effects due to the molecular structure. Additionally to the electronic excitation states which are known from atoms, molecules are able to rotate and to vibrate. These rotations and vibrations are quantized; there are discrete energy levels. The smallest energy differences exist between different rotational states, therefore pure rotational spectra are in the far infrared region (about 30 – 150 µm wavelength) of the electromagnetic spectrum. Vibrational spectra are in the near infrared (about 1 – 5 µm) and spectra resulting from electronic transitions are mostly in the visible and ultraviolet regions. From measuring rotational and vibrational spectra properties of molecules like the distance between the nuclei can be calculated.^[6]

As with many scientific fields, strict delineation can be highly contrived and atomic physics is often considered in the wider context of atomic, molecular, and optical physics. Physics research groups are usually so classified.

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